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Chemical and Electrochemical Deposition of 2D Boron Nitride Nanomaterial Films

University of Southampton School of Chemistry and Chemical Engineering
✓ Funded (Competition) 🎓 Applied Chemistry 🎓 Electronic Engineering 🎓 Inorganic Chemistry 🎓 Physical Chemistry nanomaterials 2d materials boron nitride chemical vapor deposition electrochemical deposition semiconductors neuromorphic computing memristors

Explore chemical and electrochemical techniques to grow 2D boron nitride insulating films for advanced semiconductor devices. Investigate their integration with 2D semiconductors and applications in neuromorphic computing.

AI-generated overview

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Why This Research Matters

Developing reliable methods to grow insulating 2D boron nitride films is vital for fabricating next-generation semiconductor devices with improved interfaces and functional properties. Such advances support emerging technologies like memristors, which are key to neuromorphic computing, potentially revolutionizing computing architectures and energy efficiency.

Chemistry

Project Description

Project Overview

This research is part of a large multidisciplinary project on 2D semiconductors, focusing on the 2D insulator boron nitride, also known as “white graphene” due to its structural similarity but insulating properties. The project develops chemical vapor and pioneering electrochemical deposition methods to grow hexagonal boron nitride on flat conducting or insulating surfaces. Subsequent growth of 2D semiconductors over boron nitride films will be studied to evaluate effects on semiconductor properties.

What You Will Do

The student will handle air-sensitive precursors for materials deposition and employ structural, compositional, and functional characterization techniques. Training in electrochemistry will be provided through Southampton’s MSc and summer school programmes. Research activities will take place within the Schools of Chemistry and Chemical Engineering, and Electronics and Computer Science, in collaboration with teams at Southampton and Warwick.

Expected Outcomes

The project will produce novel growth methods for 2D boron nitride films and demonstrate their integration with 2D semiconductors grown electrochemically. Functional evaluation of these heterostructures will provide insights for applications such as memristors in neuromorphic computing technologies.

Why This Matters

2D boron nitride offers an ideal insulating surface for next-generation 2D semiconductor devices, enabling van der Waals epitaxy and functional device architectures. Advances in deposition techniques and understanding of semiconductor-boron nitride interfaces are critical for future electronics, particularly in emerging neuromorphic computing systems.

Entry Requirements

UK 2:1 honours degree or international equivalent in chemistry or a closely related discipline.

How to Apply

Apply through the University of Southampton application portal for the PhD Chemistry programme (code 7189) under Faculty of Engineering and Physical Sciences for 2026/27. Applications must include CV, two academic references, degree transcripts and certificates, and English language qualification if applicable. Contact feps-pgr-apply@soton.ac.uk for general enquiries; contact A.L.Hector@soton.ac.uk for project-specific questions.

Eligibility

UK/Home
EU
International

Supervisor Profile

PA
Professor Andrew Hector
University of Southampton, School of Chemistry and Chemical Engineering
6770 Citations
47 h-index
Google Scholar

Prof. Andrew Hector is a leading researcher at the University of Southampton specializing in chemistry with extensive experience in materials synthesis and characterization, particularly nitrides and related compounds. His research focuses on understanding structural and compositional variations in advanced materials and their applications, with over 6700 citations and an h-index of 47. He collaborates widely on multidisciplinary projects involving electrochemical growth and materials chemistry.

Key Publications

2004 250 citations
Synthesis and structural study of stoichiometric Bi2Ti2O7 pyrochlore
2013 185 citations
Nitrogen-rich transition metal nitrides
2018 160 citations
Understanding and development of olivine LiCoPO 4 cathode materials for lithium-ion batteries
2006 136 citations
Structural and compositional variations in Ta3N5 produced by high-temperature ammonolysis of tantalum oxide
2009 111 citations
Synthesis and applications of nanocrystalline nitride materials

Research Contributions

Synthesized and structurally characterized pyrochlore materials such as Bi2Ti2O7.
Contributed to understanding material structures important for advanced ceramics and electronic applications.
Developed and studied nitrogen-rich transition metal nitrides and their applications.
Enabled advancements in materials for catalysis and energy storage technologies.
Investigated olivine LiCoPO4 cathode materials for lithium-ion batteries.
Supported development of improved battery materials with enhanced performance.
Explored synthesis and properties of nanocrystalline nitride materials.
Advanced applications in supercapacitors and electronic devices using nanomaterials.

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