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TUO

Electrolyte Engineering for Next-Generation Batteries Using NMR and Electrochemical Techniques

✓ Fully Funded ⏰ Closing Soon 🎓 Chemical Engineering 🎓 Chemistry 🎓 Materials Science electrochemistry energy storage ion transport batteries electrolyte engineering nmr spectroscopy battery failure mechanisms temperature-dependent transport

Explore the ion transport and failure modes in battery electrolytes using advanced NMR and electrochemical techniques. Develop next-generation batteries with improved safety and performance in cold and extreme environments.

AI-generated overview

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Why This Research Matters

This research addresses critical challenges in battery performance and safety, enabling the design of electrolytes that allow faster charging and reliable operation under harsh conditions. Ultimately, it supports the transition to sustainable energy by improving the durability and efficiency of batteries used in electric vehicles and renewable energy storage.

Solid-state NMR PFG-NMR Organic Battery Electrodes Electrolytes

Project Description

Project Overview

This PhD project investigates next-generation battery electrolytes to enhance performance, safety, and operation in colder climates. It focuses on ion transport mechanisms and failure modes using chemically sensitive, non-destructive nuclear magnetic resonance (NMR) techniques combined with electrochemical analysis. The objective is to probe battery electrolytes under non-equilibrium conditions to achieve ion-specific insights.

What You Will Do

The project is experimental, emphasizing NMR spectroscopy and electrochemistry to characterize battery electrolytes. It involves developing a comprehensive understanding of temperature-dependent ion transport mechanisms and electrolyte degradation pathways under various operating conditions. The candidate will gain hands-on experience with advanced analytical tools and battery analysis methods.

Expected Outcomes

Expected outcomes include elucidation of ion-specific transport phenomena, novel insights into failure mechanisms, and improved electrolyte designs tailored for specific extreme operating environments. This knowledge will inform the development of batteries with faster charging, enhanced safety, and better performance at low temperatures.

Why This Matters

Batteries are critical for clean energy technologies. Understanding electrolyte behavior under real-world conditions enables the design of safer, more efficient energy storage solutions essential for sustainability goals and expanding battery applications in diverse climates and industries.

Entry Requirements

A two-year master's degree (120 ECTS points) or equivalent in chemistry, chemical engineering, materials science, or related fields. Prior knowledge of NMR and/or electrochemistry preferred but not required. Proficiency in spoken and written English is essential.

How to Apply

Submit a single PDF containing a cover letter, CV, academic transcripts and degree certificates (in English), and a writing sample by June 12, 2026. Apply online via the 'Apply now' link. For questions contact Assistant Professor Leo W. Gordon at lewigo@kemi.dtu.dk.

Eligibility

UK/Home
EU
International

Supervisor Profile

AP
Assistant Professor Leo W. Gordon
Technical University of Denmark, Chemistry

Assistant Professor Leo W. Gordon specializes in electrolyte engineering for energy storage systems, focusing on understanding ion transport phenomena and degradation mechanisms in next-generation batteries. His research integrates advanced nuclear magnetic resonance spectroscopy with electrochemical methods to elucidate complex material behaviors. He is recognized for his interdisciplinary approach in advancing battery science and clean energy technologies.

Key Publications

2022 388 citations
Disentangling faradaic, pseudocapacitive, and capacitive charge storage: a tutorial for the characterization of batteries, supercapacitors, and hybrid systems
2022 37 citations
Formation of a CoMn‐layered double hydroxide/graphite supercapacitor by a single electrochemical step
2024 25 citations
Solid polymer electrolytes with enhanced electrochemical stability for high‐capacity aluminum batteries
2022 21 citations
Soluble electrolyte-coordinated sulfide species revealed in Al–S batteries by nuclear magnetic resonance spectroscopy
2023 20 citations
Reversible zinc electrodeposition at− 60° C using a deep eutectic electrolyte for low-temperature zinc metal batteries

Research Contributions

Developed methodologies to disentangle faradaic, pseudocapacitive, and capacitive charge storage mechanisms in batteries and supercapacitors.
This enables improved characterization and optimization of energy storage devices for enhanced performance.
Created novel solid polymer electrolytes with enhanced electrochemical stability for aluminum batteries.
Improved electrolyte stability contributes to higher capacity and safer aluminum battery technologies.
Investigated electrolyte speciation and coordinated sulfide species in aluminum-sulfur batteries using NMR spectroscopy.
Provides molecular-level insights that support the design of better-performing aluminum-sulfur battery chemistries.
Demonstrated reversible zinc electrodeposition at very low temperatures using deep eutectic electrolytes.
Advances the development of low-temperature zinc metal batteries suitable for cold climate applications.

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