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PhD in Photocatalysis: Development of Organic Synthetic Methodologies Using Earth-Abundant Metal Catalysts

Self-funded ⏰ Closing Soon 🎓 Chemistry organic synthesis photocatalysis sustainable chemistry earth-abundant metals photoredox catalysis iron catalysis visible light catalysis organometallic chemistry

Explore sustainable organic synthesis using Earth-abundant metal photocatalysts under visible light. Develop new green chemical methodologies in a state-of-the-art research group at University of Murcia. Advance photocatalysis beyond precious metals to impact pharmaceuticals and materials.

AI-generated overview

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Why This Research Matters

This research contributes to global sustainability challenges by creating greener, more eco-friendly chemical processes that reduce the reliance on precious metals. The development of Earth-abundant metal photocatalysts has potential to revolutionize pharmaceuticals, materials science, and industrial chemistry, supporting environmentally responsible manufacturing practices.

homogeneous catalysis organic synthesis photocatalysis

Project Description

Project Overview

This PhD project focuses on developing novel organic synthetic methodologies using Earth-abundant metal photocatalysts, specifically targeting first-row transition metals. The aim is to harness renewable energy sources like visible light and electricity to create sustainable, green chemical processes that go beyond traditional photoredox catalysis.

What You Will Do

The candidate will join Dr. Francisco Juliá-Hernández’s research group, which specializes in organic synthesis, organometallic catalysis, and photocatalysis. Using advanced experimental facilities and instrumentation (HPLC, GC-MS, gloveboxes), the student will design and test iron-based photocatalytic systems to develop new sustainable synthetic routes.

Expected Outcomes

The project expects to deliver innovative, environmentally friendly organic synthetic methods with broad applicability in industrial chemistry, pharmaceuticals, and materials science. The methodologies developed are anticipated to reduce dependence on precious metals and promote greener chemical manufacturing.

Why This Matters

This research addresses the urgent global challenge of developing sustainable chemical processes, contributing to greener manufacturing and reduced environmental impact. Leveraging Earth-abundant metals and renewable energy sources could transform synthetic chemistry by making it more eco-friendly and economically viable.

Entry Requirements

Completed or near-completed MSc degree in Chemistry. Experience in organic synthesis, photocatalysis, radical chemistry, organometallic chemistry, and/or homogeneous catalysis highly desirable. Strong motivation for sustainable chemistry and teamwork skills required.

How to Apply

Prepare a one-page cover letter, CV, academic transcripts, and contact details of two academic referees. Send applications as per instructions in the original LinkedIn post: https://www.linkedin.com/posts/francisco-julia-hernandez_%F0%9D%97%A3%F0%9D%97%B5%F0%9D%97%97-%F0%9D%97%A3%F0%9D%97%BC%F0%9D%98%80%F0%9D%97%B6%F0%9D%98%81%F0%9D%97%B6%F0%9D%97%BC%F0%9D%97%BB-%F0%9D%97%AE%F0%9D%98%83%F0%9D%97%AE%F0%9D%97%B6%F0%9D%97%B9%F0%9D%97%AE%F0%9D%97%AF%F0%9D%97%B9%F0%9D%97%B2-share-7453388178549424128-cg81

Eligibility

UK/Home
EU
International

Supervisor Profile

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Dr. Francisco Juliá-Hernández
University of Murcia

Dr. Francisco Juliá-Hernández leads a dynamic research group at the University of Murcia specializing in organic synthesis, organometallic catalysis, and photocatalysis. His work centers on developing innovative photocatalytic methodologies involving Earth-abundant metals like iron. His group is recognized for cutting-edge research published in high-impact journals such as Angewandte Chemie and Nature Communications, emphasizing sustainable and practical synthetic applications.

Key Publications

2018 684 citations
Transition‐metal‐catalyzed carboxylation reactions with carbon dioxide
Reviewed transition-metal-catalyzed carboxylation reactions using carbon dioxide, advancing the understanding of CO2 utilization in organic synthesis.
2018 530 citations
Walking metals for remote functionalization
Developed strategies for remote functionalization using transition metals, enabling selective modification of molecules at distant sites.
2017 462 citations
Remote carboxylation of halogenated aliphatic hydrocarbons with carbon dioxide
Demonstrated the remote carboxylation of halogenated hydrocarbons with CO2, facilitating the incorporation of CO2 into organic molecules at distant positions.
2017 324 citations
Site-Selective Catalytic Carboxylation of Unsaturated Hydrocarbons with CO2 and Water
Showed site-selective carboxylation of unsaturated hydrocarbons using CO2 and water, providing a method for selective functionalization.
2016 174 citations
Room-Temperature Direct β-Arylation of Thiophenes and Benzo[b]thiophenes and Kinetic Evidence for a Heck-type Pathway
Established a room-temperature method for β-arylation of thiophenes via a Heck-type pathway, expanding substrate scope in cross-coupling chemistry.

Research Contributions

Developed transition-metal-catalyzed carboxylation methods that utilize carbon dioxide as a carbon source.
These methods provide sustainable approaches for incorporating CO2 into value-added organic compounds, addressing environmental and synthetic challenges.
Advanced remote functionalization techniques via metal walking strategies.
Enabled selective modification of remote C–H bonds in complex molecules, enhancing synthetic flexibility.
Established site-selective and regioselective catalytic transformations including carboxylation and arylation reactions.
Improved precision in organic synthesis, allowing for targeted modifications important for pharmaceuticals and materials.

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